摘要
Abstract
2,4,6-Trinitro-3,5-diamino-N-(1,2,4-triazole-4)-aniline was synthesized using 2,4,6-trinitrochlorobenzene as the start material which firstly reacted with methylamine alcohol solution, then reacted with sulfuric acid and nitric acid, and finally reacted with 4-amino-1,2,4-triazole(ATA) and methanol sodium.The total yield is 80.18%.The target compound and its intermediates were identified by IR, MS and 1 H NMR.The main affecting factors of the reactions were discussed based on reaction mechanism. The results of the DSC test show that the two thermal decomposition peak temperature are respectively 210 ℃ and 328 ℃.The results of the TG test show that there is not any obvious quality loss process below 200 ℃, and the residual decomposition is 38.89%when the temperature is up to 500 ℃, indicating the final compoud has good thermal stability.关键词
有机化学/2,4,6-三硝基氯苯/2,4,6-三硝基-3,5-二氨基-N-(1,2,4-三唑-4)-苯胺/含能材料/合成Key words
organic chemistry/2,4,6-trinitrochlorobenzene/2,4,6-trinitro-3,5-diamino-N-(1,2,4-triazole-4)-aniline/energetic materials/synthesis分类
军事科技
