含能材料Issue(6)：821-824,4.DOI:10.3969/j.issn.1006-9941.2013.06.026
3，3′-二（四唑-5-基）-4，4′-偶氮呋咱及其含能离子盐的合成及热性能
Synthesis and Thermal Properties of 3,3′-Bis(tetrazol-5-yl)-4,4′-azofurazan and Its Energetic Salts
摘要
Abstract
3,3′-Bis(tetrazol-5-yl)-4,4′-azofurazan(DTZAF) was synthesized from 3-amino-4-(tetrazol-5-yl)furazan, and its four energetic salts were then synthesized via metathesis reaction with total yield of 73.0%, 70.3%, 75.0%, 76.3%.Theri structures were characterized by IR, 13 C NMR, 1 H NMR, MS and elemental analysis.Their thermal decomposition products were studied by TG-DSC-IR-MS.The thermal prpperties of DTZAF and its energetic salts were studied by differential scanning calorimetry(DSC) and thermogravimetry(TG).Results show that DTZAF and its energetic salts have good thermal stability before 200 ℃.关键词
有机化学/含能离子盐/合成/热性能Key words
organic chemistry/energetic salts/synthesis/thermal property分类
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李辉,于倩倩,王伯周,来蔚鹏,葛忠学,李亚南,刘宁..3，3′-二（四唑-5-基）-4，4′-偶氮呋咱及其含能离子盐的合成及热性能[J].含能材料,2013,(6):821-824,4.基金项目
国防科工局基础科研项目 （）
