含能材料Issue(1)：126-128,3.DOI:10.3969/j.issn.1006-9941.2014.01.025
1，3，5-三硝基-2，3-二氢-1H-咪唑并［4，5-b］吡啶-2-酮的合成及热分解
Synthesis and Thermal Behavior of 1,3,5-Trinitro-2,3-dihydro-1H-imidazo-[4,5-b]pyridin-2-one
马丛明 1刘祖亮 1姚其正1
作者信息
- 1. 南京理工大学化工学院，江苏 南京 210094
- 折叠
摘要
Abstract
2,3-Dihydro-1H-imidazo[4,5-b]pyridin-2-one(1)was synthesized by ring-closing reaction using 2,3-diaminopyridine as primary material. A novel compound 1,3,5-trinitro-2,3-dihydro-1H-imidazo-[4,5-b]pyridin-2-one(2)was obtained with it by nitration in the system of HNO3/Ac2O,with a yield of 44.6%. Their structures were characterized by 1H NMR,MS and IR,and thermal behavior of compound 2 was studied by differential scanning calorimetry and thermogravimetry. Results show decomposi-tion temperature of compound 2 is 153. 0 ℃,and the mass loss due to overall reaction(130 ~450 ℃)is 55. 5%,indicating poor heat stability of compound 2.关键词
有机化学/合成/热分解/含能化合物Key words
organic chemistry/synthesis/thermal behavior/energetic material分类
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马丛明,刘祖亮,姚其正..1，3，5-三硝基-2，3-二氢-1H-咪唑并［4，5-b］吡啶-2-酮的合成及热分解[J].含能材料,2014,(1):126-128,3.
