井冈山大学学报(自然科学版)Issue(2):27-30,4.DOI:10.3969/j.issn.1674-8085.2014.02.006
Fe(III)树脂催化水合肼还原法制备氧化偶氮苯类化合物
PREPARATION OF AZOXY COMPOUNDS BY HYDRAZINE HYDRATE REDUCTION CATALYZED WITH FE(III) RESIN
摘要
Abstract
Azoxy compounds were prepared in 23%~99% yields from aromatic nitro compounds by hydrazine hydrate reduction in the presence of Fe(III) resin, which was prepared by cation exchanging between 10%FeCl3 solution and D72 macroporous cation resin. The Hammet constant of reactant has a great influence on the yield of target product. The yield is higher with the larger Hammet constant.关键词
氧化偶氮苯/阳离子树脂/水合肼/还原Key words
azoxybenzene/cation resin/hydrazine hydrate/reduction分类
化学化工引用本文复制引用
蔡可迎,王丽..Fe(III)树脂催化水合肼还原法制备氧化偶氮苯类化合物[J].井冈山大学学报(自然科学版),2014,(2):27-30,4.基金项目
徐州工程学院科研项目 ()