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废钨渣中钽、铌、钨高效共提新工艺研究

汪加军 王晓辉 黄波 郑诗礼

有色金属科学与工程Issue(5):91-96,6.
有色金属科学与工程Issue(5):91-96,6.

废钨渣中钽、铌、钨高效共提新工艺研究

New process of high efficient co-extraction of tantalum, niobium and tungsten from tungsten residue

汪加军 1王晓辉 2黄波 1郑诗礼2

作者信息

  • 1. 中国矿业大学 北京化学与环境工程学院,北京 100083
  • 2. 中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室,绿色过程与工程院重点实验室,北京 100190
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摘要

Abstract

This paper describes a new technology for co-extracting tantalum, niobium and tungsten from tungsten residue using fluoride salt transformation-HF-H 2SO4 leaching-fluoride salt recycling through ammonia conversion.The optimal technical conditions are ensured by experiments. Under the optimal condition, an enriched material with the contents of Ta2O5 and Nb2O5 are 6.08 % and 27.29 % respectively and an enriched material with the content of WO3 is 26.71 % are gained. The single pass recovery rates of tantalum, niobium and tungsten are 83.18 %, 88.33 % and 77.91 %, respectively. This technology process is simple with mild operation conditions. This new process offers a favorable technical economic value due to the recycling use of the fluoride salt and low cost materials consumption.

关键词

钨渣///氟盐/富集

Key words

tungsten residue/tantalum/niobium/fluoride salt/enrichment

分类

矿业与冶金

引用本文复制引用

汪加军,王晓辉,黄波,郑诗礼..废钨渣中钽、铌、钨高效共提新工艺研究[J].有色金属科学与工程,2013,(5):91-96,6.

基金项目

国家自然科学基金资助项目 ()

有色金属科学与工程

OACSTPCD

1674-9669

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