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活性炭对汞离子的吸附动力学研究

卢辛成 蒋剑春 孙康 谢新苹 张艳萍 王金表

生物质化学工程Issue(2):1-7,7.
生物质化学工程Issue(2):1-7,7.DOI:10.3969/j.issn.1673-5854.2014.02.001

活性炭对汞离子的吸附动力学研究

Kinetics Studies on Adsorption of Hg2+ by Activated Carbon

卢辛成 1蒋剑春 1孙康 1谢新苹 1张艳萍 1王金表1

作者信息

  • 1. 中国林业科学研究院林产化学工业研究所 生物质化学利用国家工程实验室 国家林业局林产化学工程重点开放性实验室 江苏省生物质能源与材料重点实验室,江苏 南京 210042
  • 折叠

摘要

Abstract

Activated carbon with micropores was prepared from coconut carbon using steam activation by secondary activation. N2-adsorption isotherm, mathematical models such as D-R equation and BJH methods were used to characterize the properties of the prepared activated carbons. With mercury chloride as pollution targets, the adsorption properties of activated carbon for Hg2+were investigated. The results indicated that the adsorption of Hg2+ was obviously influenced by surface area and pore structure of activated carbon. The process of adsorption was a two speed process with rapidly adsorption and slowly adsorption coexisting. This process could be well described by Lagergren pseudo second order model. The adsorption isotherm experiment showed that adsorption of Hg2+ on activated carbon is an exothermic and single molecular layer adsorption process. It could be fitted by Langmuir isotherm model.

关键词

活性炭/氯化汞/比表面性质/吸附动力学/吸附等温线

Key words

activated carbon/mercury chloride/specific surface properties/adsorption kinetics/adsorption isotherm

分类

化学化工

引用本文复制引用

卢辛成,蒋剑春,孙康,谢新苹,张艳萍,王金表..活性炭对汞离子的吸附动力学研究[J].生物质化学工程,2014,(2):1-7,7.

基金项目

中央级公益性科研院所基本科研业务费专项资金(CAFINT2013C02) (CAFINT2013C02)

江苏省自然科学基金(BK2012514) (BK2012514)

生物质化学工程

OA北大核心

1673-5854

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