林产化学与工业Issue(1)：57-61,5.DOI:10.3969/j.issn.0253-2417.2014.01.010
碱木质素过氧化氢预处理制备驱油剂的研究
Preparation of Surfactants for Enhanced Oil Recovery from Alkali Lignin Pretreated with Hydrogen Peroxide
摘要
Abstract
The method for synthesis of surfactants for enhance d oil recovery, including pretreatment with H2 O2 , sulfonation, amination and alkylation, was studied with alkali lignin as feedstock. Firstly, the effects of pretreatment conditions on surface tension were investigated. The suitable pretreatment conditions were that mass ratio of H2 O2 to alkali lignin was 1:10 at 70℃ for 30 min. Under the pretreatment conditions, the surface tension of 0. 9 % surfactant solution could be reduced to 24 mN/m. The effects of surfactant and alkali concentration on oil-water interfacial tension of Gudao crude oil were also studied. The results showed that when both the surfactant concentration and NaOH concentration was 0. 4 %, the oil-water interfacial tension was decreased to 0. 07 mN/m. It was more stable than the control surfactants synthesized without H2 O2 pretreatment. Finally, Fourier Transform Infrared ( FT-IR) analysis indicated the structural characterization of lignin before and after modification.关键词
碱木质素/氧化/表面张力/油/水界面张力Key words
alkali lignin/oxidation/surface tension/oil-water interfacial tension分类
化学化工引用本文复制引用
申士成,周玉杰,米杰,张建安,戴玲妹,刘德华,CHOO Y M,LOH S K..碱木质素过氧化氢预处理制备驱油剂的研究[J].林产化学与工业,2014,(1):57-61,5.基金项目
国家自然科学基金资助项目(21176141) （21176141）
国家973计划资助(2011CB707406) （2011CB707406）
马来西亚棕榈油协会资助项目(无编号) （无编号）
