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构造煤甲烷吸附表面能研究

简阔 张玉贵 赫少攀 高然超

煤田地质与勘探Issue(1):31-34,39,5.
煤田地质与勘探Issue(1):31-34,39,5.DOI:10.3969/j.issn.1001-1986.2014.01.007

构造煤甲烷吸附表面能研究

The surface energy of methane adsorption of tectonic coal

简阔 1张玉贵 1赫少攀 1高然超1

作者信息

  • 1. 河南理工大学安全科学与工程学院,河南 焦作 454000
  • 折叠

摘要

Abstract

The fundamental reason of coal adsorption difference is coal surface energy. In this paper, the effect which is from dynamic metamorphism on tectonic coal structure and components was analyzed. In the process of adsorption of methane, using methane adsorption isotherm experiments, we calculated the surface energy change of primary structure coal and tectonic coal at different temperatures, and causes of surface energy change of tectonic coal were analyzed from the perspective of dynamic metamorphism. The results show that the transformable effect which is from dynamic metamorphism on structure and components of tectonic coal is obvious, the micro pores structure of tectonic coal is more developed than symbiotic primary structure coal, and the tectonic coal has stronger adsorption capacity. The calculation results also show that, both the lower value of surface energy and ad-sorption methane capacity of tectonic coal are .larger than symbiotic primary structure coal with the increase of temperature and pressure.

关键词

构造煤/动力变质作用/甲烷吸附表面能

Key words

tectonic coal/dynamic metamorphism/the surface energy of methane adsorption

分类

天文与地球科学

引用本文复制引用

简阔,张玉贵,赫少攀,高然超..构造煤甲烷吸附表面能研究[J].煤田地质与勘探,2014,(1):31-34,39,5.

基金项目

国家科技重大专项课题(2011ZX05040-005);国家自然科学基金项目(41102094) (2011ZX05040-005)

煤田地质与勘探

OA北大核心CSCDCSTPCD

1001-1986

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