煤田地质与勘探Issue(1):31-34,39,5.DOI:10.3969/j.issn.1001-1986.2014.01.007
构造煤甲烷吸附表面能研究
The surface energy of methane adsorption of tectonic coal
摘要
Abstract
The fundamental reason of coal adsorption difference is coal surface energy. In this paper, the effect which is from dynamic metamorphism on tectonic coal structure and components was analyzed. In the process of adsorption of methane, using methane adsorption isotherm experiments, we calculated the surface energy change of primary structure coal and tectonic coal at different temperatures, and causes of surface energy change of tectonic coal were analyzed from the perspective of dynamic metamorphism. The results show that the transformable effect which is from dynamic metamorphism on structure and components of tectonic coal is obvious, the micro pores structure of tectonic coal is more developed than symbiotic primary structure coal, and the tectonic coal has stronger adsorption capacity. The calculation results also show that, both the lower value of surface energy and ad-sorption methane capacity of tectonic coal are .larger than symbiotic primary structure coal with the increase of temperature and pressure.关键词
构造煤/动力变质作用/甲烷吸附表面能Key words
tectonic coal/dynamic metamorphism/the surface energy of methane adsorption分类
天文与地球科学引用本文复制引用
简阔,张玉贵,赫少攀,高然超..构造煤甲烷吸附表面能研究[J].煤田地质与勘探,2014,(1):31-34,39,5.基金项目
国家科技重大专项课题(2011ZX05040-005);国家自然科学基金项目(41102094) (2011ZX05040-005)