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稻草固定床热解过程中不同赋存状态钾的迁移转化行为

赵英杰 陈雪莉 陈汉鼎 刘海峰

燃料化学学报Issue(4):427-433,7.
燃料化学学报Issue(4):427-433,7.

稻草固定床热解过程中不同赋存状态钾的迁移转化行为

Transfer of potassium in different forms during pyrolysis of rice straw in a fixed bed reactor

赵英杰 1陈雪莉 1陈汉鼎 1刘海峰1

作者信息

  • 1. 华东理工大学煤气化及能源化工教育部重点实验室 上海市煤气化工程技术研究中心,上海 200237
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摘要

Abstract

Three materials including raw and water-washed ice straw, and microcrystalline cellulose with 5%KCl loaded were pyrolysed in the fixed bed reactor to investigate the transfer of potassium in four forms. The results indicate that the release of potassium changes little with pyrolysis temperature below 700 ℃, and the release of potassium dramatically increases with pyrolysis temperature above 700 ℃. During the rice straw pyrolysis, the transfer of four forms of potassium takes place, in which the water soluble and the potassium in residue decrease. It is confirmed that the potassium combined with carbon can be partly changed to water soluble, and the water soluble and organically bound potassium can exchange each other during pyrolysis.

关键词

稻草/固定床/热解//赋存状态/迁移转化

Key words

biomass/fixed-bed/pyrolysis/potassium/speciation/transform and transport

分类

能源科技

引用本文复制引用

赵英杰,陈雪莉,陈汉鼎,刘海峰..稻草固定床热解过程中不同赋存状态钾的迁移转化行为[J].燃料化学学报,2014,(4):427-433,7.

基金项目

国家自然科学基金(21306050) (21306050)

国家科技支撑计划(2012BAA09B02) (2012BAA09B02)

新世纪优秀人才支持计划(NCET-12-0854)。 (NCET-12-0854)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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