四川大学学报(自然科学版)Issue(6):1277-1284,8.DOI:10.3969/j.issn.0490-6756.2013.06.021
4d波函数塌缩对类Kr离子4p6→4p5nd辐射跃迁性质影响研究
Theoretical study on the effect of the collapse of the 4d-wavefunction on 4 p6 →4 p5 nd transition probabilities of Kr-like ions
摘要
Abstract
Self-consistent-field calculations of the 4 d electron radial wave function for Kr atom isoelec-tronic sequence ions have been made using relativistic Hartree-Fork (HFR) and LS-dependent HFR methods including correlation and configuration interaction .And orbital radii and the transition energies and oscillator strengths of the 4p6 →4p5 nd (4≤ n≤8) have been computed in Kr-like ions .The results show that the collapse of the 4d-wave functions start from Rb+ in Kr-like ions .The collapse of the 4d-wave functions for Rb+ 、Sr2+ 、Y3+ is partial collapse .It is found that the oscillator strengths of the 4p6→4p54d are very strong for ions in 4d-wavefunction collapse and the oscillator stregths of the 4p6 →4p5 5 d ,6 d ,7 d are also stronger for ions in 4 d-wavefunctions partial collapse .And it is found that the bulk of transition oscillator strengths is concentrated at the 4p6 →4p54d after 4d-wave function is completely collapsed .关键词
波函数/塌缩/部分塌缩/跃迁能/振子强度Key words
wave functions/collapse/partial collapse/transition energies/oscillator strengths分类
数理科学引用本文复制引用
李继弘..4d波函数塌缩对类Kr离子4p6→4p5nd辐射跃迁性质影响研究[J].四川大学学报(自然科学版),2013,(6):1277-1284,8.基金项目
陇东学院科研项目基金 ()