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5-安替吡啉偶氮水杨基荧光酮的合成及其与钒(Ⅴ)的显色反应

郝登越 于秀兰 张嘉月

湿法冶金Issue(6):421-424,4.
湿法冶金Issue(6):421-424,4.

5-安替吡啉偶氮水杨基荧光酮的合成及其与钒(Ⅴ)的显色反应

Synthesis of 5-antipyriy lazosalicyl fluoroneand and Its Color Rreaction With Vanadium (Ⅴ)

郝登越 1于秀兰 1张嘉月1

作者信息

  • 1. 沈阳化工大学应用化学学院,辽宁沈阳 110142
  • 折叠

摘要

Abstract

The 5-antipyriylazosalicylfluoroneand(APASF) was synthesized ,and optimum color reaction conditions of 5-antipyriylazosalicylfluoroneand (APASF ) with vanadium (Ⅴ ) were determined .The results showed that the color reagent reacts with vanadium (Ⅴ) to form a stable claret complex (3∶1) in buffer solution HAc-NH4Ac at pH = 6 .8 .The maxiumum absorption wavelength and apparent molar absorptivity are 550 nm and 3 .08 × 104 L · mol-1 · cm -1 ,respectively .The Beer’s law is obeyed in the range of 0-30 μg/25mL for vanadium (Ⅴ) .

关键词

5-安替吡啉偶氮水杨基荧光酮/钒(Ⅴ)/分光光度法

Key words

5-antipyriylazosalicylfluoroneand/vanadium(Ⅴ)/spectrophotometry

分类

化学化工

引用本文复制引用

郝登越,于秀兰,张嘉月..5-安替吡啉偶氮水杨基荧光酮的合成及其与钒(Ⅴ)的显色反应[J].湿法冶金,2013,(6):421-424,4.

湿法冶金

OA北大核心

1009-2617

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