石油化工高等学校学报Issue(1)：17-21,5.DOI:10.3969/j.issn.1006-396X.2014.01.004
油浆抽提油在Ni-Mo／SiO2-Al2O3催化剂上加氢脱除PAHs动力学
Kinetics of Selective Hydrogenation of PA Hs in the Extracted FCCS over Ni-M o/SiO2-Al2 O3 Catalyst
摘要
Abstract
Selective hydrogenation of PAHs in the extracted FCCS over Ni-Mo/SiO2-Al2 O3 catalyst was studied in a high pressure batch autoclave .Experiments were carried out under the conditions of reaction temperature 260~320 ℃ ,hydrogen pressure 4~7 MPa ,reaction time 2~6 h and the ratio of catalyst to oil 0 .2~0 .5 .According to the most important factors of selective hydrogenation of PAHs ,the power function kinetics equation was established .The Differential method and Newton iteration method were adopted to estimate the nonlinear parameters of the model .The results show that the calculated reaction order is 1 .14 and the activation energy is 44 .33 kJ/mol . The average relative deviation of experimental data and model prediction data is 1 .41% .关键词
催化裂化油浆/多环芳烃/选择性加氢/动力学方程Key words
Catalytic cracking oil slurry/Polycyclic aromatic hydrocarbons/Selective hydrogenation/Kinetics equation分类
能源科技引用本文复制引用
谷云格,崔文龙,杨基和,刘英杰..油浆抽提油在Ni-Mo／SiO2-Al2O3催化剂上加氢脱除PAHs动力学[J].石油化工高等学校学报,2014,(1):17-21,5.基金项目
化工资源有效利用国家重点实验室资助项目（CRE-2013-C-301）。 （）
