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Gemini型表面活性剂三元复合体系性能和驱油效果

范海明 孟祥灿 郁登朗 杨丹丹 康万利 徐海

石油化工高等学校学报Issue(1):79-83,5.
石油化工高等学校学报Issue(1):79-83,5.DOI:10.3969/j.issn.1006-396X.2014.01.016

Gemini型表面活性剂三元复合体系性能和驱油效果

Physicochemical Properties and Oil Displacement Efficiency of Gemini Surfactant ASP Flooding

范海明 1孟祥灿 1郁登朗 2杨丹丹 3康万利 1徐海1

作者信息

  • 1. 中国石油大学 华东 石油工程学院,山东青岛266580
  • 2. 中国石化胜利油田分公司采油工艺研究院,山东东营257000
  • 3. 吉林油田新民采油厂,吉林松原138000
  • 折叠

摘要

Abstract

The anionic Gemini surfactant Sodium dioleoylamino cystine (SDOLC) was synthesized by one-step reaction of sodium cystine and oleoyl chloride .The reducing oil/water interfacial tension properties and viscoelastic properties of Gemini/HPAM/alkali mixed system were investigated by Texas-500C spinning drop interface tensiometer and MCR301 rheometer ,and the oil displacement efficiency in homogeneous and heterogeneous cores were evaluated . It was found that the minimum dynamic interfacial tension magnitude between Daqing crude oil and Gemini surfactant/alkali mixed solution is not affected with the addition of HPAM ,but the viscosities increased .Overall considering the interfacial tension and viscosity ,mixed solution including mass fraction of 0 .18% HPAM ,0 .1% SDOLC ,0 .15% NaOH and 0 .06% HEDP · Na4 was chose as Gemini surfactant ASP flooding system .The viscosity of this system was 44 mPa · s and oil/water interfacial tension was 2 .4 × 10-2 mN/m .Homogeneous and heterogeneous cores were water flooded until 98% water cut ,and then were treated by 0 .6 PV Gemini surfactant ASP slug followed by water flooding to give an enhanced oil recovery of 26 .11% and 22 .25% ,respectively .

关键词

Gemini表面活性剂/三元复合驱/界面张力/黏弹性能/驱油效果

Key words

Gemini surfactant/ASP flooding/Interfacial tension/Viscoelasticity/Oil displacement efficiency

分类

能源科技

引用本文复制引用

范海明,孟祥灿,郁登朗,杨丹丹,康万利,徐海..Gemini型表面活性剂三元复合体系性能和驱油效果[J].石油化工高等学校学报,2014,(1):79-83,5.

基金项目

长江学者和创新团队发展计划项目(IRT 1294);国家自然科学基金项目(51104169);山东省自然科学基金项目(ZR2010EZ006,ZR2010BQ003);中央高校基本科研业务费专项资金项目(13CX02045A);山东省“泰山学者”建设工程项目(ts20070704)。 ()

石油化工高等学校学报

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1006-396X

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