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合成气完全甲烷化催化剂的放大制备及失活机理研究

刘志红 徐亚荣 徐新良 刘平

石油与天然气化工Issue(6):606-609,4.
石油与天然气化工Issue(6):606-609,4.DOI:10.3969/j.issn.1007-3426.2013.06.012

合成气完全甲烷化催化剂的放大制备及失活机理研究

Magnified preparation of catalyst and deactivation mechanism study of syngas methanization

刘志红 1徐亚荣 2徐新良 2刘平3

作者信息

  • 1. 中国石油天然气股份公司科技管理部
  • 2. 中国石油乌鲁木齐石化公司研究院
  • 3. 中国科学院山西煤化所
  • 折叠

摘要

Abstract

Magnified preparation of the catalyst was studied in this paper .Activity and stabili-ty of the catalyst were evaluated through long period ,and deactivation mechanism of the catalyst was studied .The study result showed that average conversion of CO and H2 reached 99 .9% and 99 .8% respectively ,average selectivity of CH4 attained 98 .5% ,and the activity of application catalyst was stable after continuous running of 1 000 hours .Deactivation mechanism study of the catalyst showed that the causes of catalyst deactivation with long period operation were carbon deposition and sintering ,in w hich sintering is the main factor resulting in the decrease of catalyst activity .

关键词

甲烷化/催化剂/放大制备/失活/机理

Key words

methanization/catalyst/magnified preparation/deactivation/mechanism

分类

能源科技

引用本文复制引用

刘志红,徐亚荣,徐新良,刘平..合成气完全甲烷化催化剂的放大制备及失活机理研究[J].石油与天然气化工,2013,(6):606-609,4.

石油与天然气化工

OACSCD

1007-3426

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