天然气化工Issue(1)：16-21,31,7.
改良ADA脱硫工艺中含硫物质与ADA反应的研究
Study on reaction of sulfur-containing substances with ADA in modified stretford desulfurization Process
摘要
Abstract
In order to understand the desulfurization mechanism at microcosmic level, the reaction mechanism of sulfur-containing substances with ADA in the modified stretford process was investigated by using the cyclic voltammetry. The results showed that the ADA could directly react with sulfur-containing substances in the simulated H2S-absorbing liquid. The reaction process had a initial rapid reaction period of 5 seconds and a slow reaction period after 5 seconds. The kinetic study on the slow reaction period indicated that the reaction of sulfur-containing substances with ADA is a first-order reaction with the rate constant of 0.00175s-1.关键词
ADA/含硫物质/反应机理/循环伏安法/改良ADA脱硫工艺Key words
ADA/sulfur-containing substance/reaction mechanism/cyclic voltammetry/desulfurization/modified stretford process分类
化学化工引用本文复制引用
罗化峰,凌开成,张卫帅..改良ADA脱硫工艺中含硫物质与ADA反应的研究[J].天然气化工,2014,(1):16-21,31,7.基金项目
国家自然科学基金（21076137），山西省自然科学基金资助项目 （）
