天然气化工Issue(1)：42-46,5.
CO2与乙炔反应合成丙烯酸的可行性研究
An study on possibility to convert CO2 and acetylene to acrylic acid
张志智 1孙潇磊 2张喜文 3孙万富 3方向晨3
作者信息
- 1. 华东理工大学反应工程(联合)国家重点实验室，上海 112004
- 2. 抚顺石油化工研究院，辽宁 抚顺 113001
- 3. 抚顺石油化工研究院，辽宁 抚顺 113001
- 折叠
摘要
Abstract
Coupling CO2 and acetylene and hydrogenation to form acrylic acid is a potential route for synthesis of acrylic acid. Thermodynamic analysis indicated that the reaction could be carried on under low temperature. Synthetic experiments of acrylic acid were performed with hydrogen and formic acid as sources of hydrogen and complexes of metal with zero valence as catalysts. The results showed that formic acid helped to produce acrylic acid, but no formation of acrylic acid when hydrogen was used as hydrogen source.关键词
二氧化碳/乙炔/甲酸/丙烯酸/合成/热力学分析Key words
carbon dioxide/acetylene/formic acid/acrylic acid/synthesis/thermodynamic analysis分类
化学化工引用本文复制引用
张志智,孙潇磊,张喜文,孙万富,方向晨..CO2与乙炔反应合成丙烯酸的可行性研究[J].天然气化工,2014,(1):42-46,5.
