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一种新型宽温加氢转化催化剂的研发

李启强 李玉富 赵丹

天然气化工Issue(1):52-54,71,4.
天然气化工Issue(1):52-54,71,4.

一种新型宽温加氢转化催化剂的研发

Development of a novel wide temperature hydroconversion catalyst

李启强 1李玉富 1赵丹1

作者信息

  • 1. 西南化工研究设计院有限公司,四川 成都 610225
  • 折叠

摘要

Abstract

The wide temperature hydroconversion catalyst NS-3 was prepared by co-precipitation method using Co, Mo and Ni as active components, La as promoter and r-Al2O3 as support. Effects of reaction conditions on the performances were investigated experimentally by comparing with a commercial catalyst JT-201-1, and a 1,000 hours endurance test was carried out. The fresh and used catalysts were characterized by XRD and BET. The results showed that for the coke oven gas feedstock containing ethanethiol, ethylene and thiophene volume fractions of about 200í10-6, 2.6% and 50í10-6, respectively, the conversions of ethanethiol, thiophene and ethylene could reach 100%, above 99% and above 98%, respectively, under the reaction conditions: 350℃-500℃, 1.0MPa-2.0MPa and GHSV of 2000h-1-6000h-1, which were much better than that of the comparative catalyst. The catalyst exhibited good stability of activity and structure.

关键词

加氢转化/宽温催化剂/有机硫/烯烃/焦炉煤气/加氢脱硫/寿命试验

Key words

hydroconversion/wide temperature catalyst/organic sulfur/olefin/coke oven gas/hydrodesulfurization/life test

分类

化学工程

引用本文复制引用

李启强,李玉富,赵丹..一种新型宽温加氢转化催化剂的研发[J].天然气化工,2014,(1):52-54,71,4.

天然气化工

OA北大核心CSCDCSTPCD

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