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铈离子掺杂浓度对氯化镧(LaCl3:Ce)闪烁晶体发光性能的影响

任国浩 裴钰 吴云涛 陈晓峰 李焕英 潘尚可

物理学报Issue(3):037802-1-037802-6,6.
物理学报Issue(3):037802-1-037802-6,6.DOI:10.7498/aps.63.037802

铈离子掺杂浓度对氯化镧(LaCl3:Ce)闪烁晶体发光性能的影响

Influence of Ce doping concentration on the luminescence prop erties of LaCl3:Ce scintillation crystals

任国浩 1裴钰 2吴云涛 1陈晓峰 1李焕英 1潘尚可1

作者信息

  • 1. 中国科学院上海硅酸盐研究所,上海 201800
  • 2. 国巨电子 中国有限公司,苏州 215000
  • 折叠

摘要

Abstract

LaCl3:Ce is an excellent rare earth halide scintillation crystal discovered in the beginning of this century. Pure LaCl3 crystal and LaCl3 crystal doped with several different Ce concentrations were grown by vertical Bridgman method. Their transmission and luminescence as well as decay time were measured and compared with each other. It was found that the cut-off edge, emission wavelength as well as decay time for pure LaCl3 crystals are respectively 215 nm, 405 nm and 1 µs. This emission is explained by the self trapped exciton (STE) of LaCl3. However, with the increase of Ce concentration in the crystal, the cut-off edge of LaCl3:Ce crystal shifts to about 300 nm, and the luminescence is dominated by the emission originating from 5d-4f transition of Ce ions. Meanwhile, the increase of the luminescence intensity of Ce3+ ion emission is accompanied with the expense of STE emission, this anti-correlation between the Ce3+and STE luminescence intensity is interpreted by the energy transfer from STE to Ce ions in LaCl3:Ce scintillation crystals.

关键词

氯化镧/发光性能/掺杂效应/能量传递

Key words

LaCl3:Ce/luminescence properties/doping effect/energy transfer

引用本文复制引用

任国浩,裴钰,吴云涛,陈晓峰,李焕英,潘尚可..铈离子掺杂浓度对氯化镧(LaCl3:Ce)闪烁晶体发光性能的影响[J].物理学报,2014,(3):037802-1-037802-6,6.

基金项目

国家自然科学基金(批准号:50672109,91022028)资助的课题 (批准号:50672109,91022028)

物理学报

OA北大核心CSCDCSTPCDSCI

1000-3290

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