陕西科技大学学报（自然科学版）Issue(5)：89-93,5.
基于3，3′，4，4′-二苯酮四甲酸构筑的配位聚合物合成、晶体结构和荧光性能研究
Syntheses,structures and properties of one novel coordination polymer assembled with 3,3′,4,4′-benzophenonetetracarboxylic
摘要
Abstract
A novel zinc coordination polymer {[Cd2 (bptc)(N3 )2 (H2O)2 ] · 2H2O}n (1) (H4 bptc=3 ,3′,4 ,4′-benzophenonetetracarboxylic ,N3 = dipyridin-2-ylamine) has been dif-fuse synthesized and structurally characterized by single-crystal .Additionally ,the fluores-cent property ,and TG analysis for compound 1 were also measured and discussed .The re-sults show that complex 1 crystallizes in the monocline system ,space group C2/c with a=26 .696 (4 )Å ,b=20 .801 (4 )Å ,c=9 .552 (2 )Å ,V =5 198 .3 (17 )Å3 ,Z=4 ,R=0 .053 0 .T he bptc4 - ligands bond the Cd(II) atoms to produce an infinite linear 1D chain ,which was linked to form a 3D supramolecular network by the hydrogen bonding interactions and π-πstack interactions .关键词
3,3′,4,4′-二苯酮四甲酸/晶体结构/配位聚合物/荧光Key words
3 ,3′,4 ,4′-benzophenonetetracarboxylic/crystal structure/coordination polymer/fluerescence分类
化学化工引用本文复制引用
张亚男,李运涛,海啸..基于3，3′，4，4′-二苯酮四甲酸构筑的配位聚合物合成、晶体结构和荧光性能研究[J].陕西科技大学学报（自然科学版）,2013,(5):89-93,5.基金项目
陕西省教育厅科研计划专项项目（12JK0627）；陕西省科技厅工业攻关项目 （）
