印染助剂Issue(11)：23-26,4.
（AB）n型聚醚嵌段改性聚硅氧烷的合成及应用
Synthesis and application of (AB)n polyether block modified polysiloxane
摘要
Abstract
Polydimethylsiloxane blocked with epoxy polyether (TPEPS) was synthesized by hydrosilylation reaction of Si-H terminated polydimethylsiloxane with al yl- epoxy polyether in the catalysis of H2PtCl6- isopro-pyl alcohol. Then (AB)n polyether block modified polysiloxane (PBEMS) was synthesized by aminolysis ring opening and quaternization of TPEPS with diamino and benzyl chloride. The chemical structure of PBEMS was characterized by IR and 1H- NMR. The optimal reaction conditions were investigated and obtained as fol ows:hydrosilylation reaction temperature was 80~100 ℃, the amount of catalyst was 1 × 10- 5~3 × 10- 5 (on the mass of reactor), the amount of isopropanol was 30%~40%, reaction time was 3 h, aminolysis ring opening temper-ature was 65~75 ℃ and 5 h of reaction time. Compared with the different polysiloxane, the hydrophilicity and yel owing resistance ability of PBEMS finished fabric were obviously improved.关键词
聚醚嵌段聚硅氧烷/季铵盐/应用性能/亲水性Key words
polyether block modified polysiloxane/quaternary ammonium salt/application performance/hydrophilicity分类
化学化工引用本文复制引用
习娟,张存社,安秋凤,王前进..（AB）n型聚醚嵌段改性聚硅氧烷的合成及应用[J].印染助剂,2013,(11):23-26,4.基金项目
陕西省科技攻关项目(2011K08-17) （2011K08-17）
