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候选材料在650℃超临界水中的腐蚀行为研究

马姝丽 罗英 张强 王浩 邱绍宇

原子能科学技术Issue(3):416-421,6.
原子能科学技术Issue(3):416-421,6.DOI:10.7538/yzk.2014.48.03.0416

候选材料在650℃超临界水中的腐蚀行为研究

Study on Corrosion Behavior of Candidate Materials in 650 ℃ Supercritical Water

马姝丽 1罗英 1张强 1王浩 1邱绍宇1

作者信息

  • 1. 中国核动力研究设计院,四川 成都 610041
  • 折叠

摘要

Abstract

The general corrosion behavior of three candidate materials (347 ,HR3C and In-718 ) was investigated in 650 ℃ /25 MPa deionized water . Morphology and composition of the surface oxide film with different exposure time were observed through FEG-SEM and EDS .The phase constitute was analyzed by GIXRD .For all the test materials ,the weight loss follows typical parabolic law and the weight loss of 347 shows more than 40 times higher than that of HR3C and In-718 .The oxide film of three alloys mainly consists of Ni(Cr, Fe)2O4 .In-718 shows severe pitting and the oxide film of 347 appears significant spalling ,while HR3C has compact oxide film .In the high temperature supercritical water ,the high Cr content may enhance the general corrosion property of the alloys ,while addition of Nb may be detrimental to the pitting resistance of alloys .

关键词

不锈钢/超临界水/腐蚀行为/氧化膜

Key words

stainless steel/supercritical water/corrosion behavior/oxide film

分类

矿业与冶金

引用本文复制引用

马姝丽,罗英,张强,王浩,邱绍宇..候选材料在650℃超临界水中的腐蚀行为研究[J].原子能科学技术,2014,(3):416-421,6.

基金项目

核能开发资助项目;973计划资助项目(2007CB209800);四川省青年科技基金资助项目 ()

原子能科学技术

OA北大核心CSCDCSTPCD

1000-6931

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