中国电机工程学报Issue(11)：1762-1768,7.DOI:10.13334/j.0258-8013.pcsee.2014.11.007
载溴高硫石油焦活性炭脱汞实验研究
Experimental Study on Mercury Removal of High-Sulfur Petroleum Coke Activated Carbon Impregnated With Bromine
摘要
Abstract
As a petrochemical industry by-product, petroleum coke with high sulfur content was made into activated carbon, and then treated by NH4Br solution for modification with Br uploading on its surface. The prepared petroleum cokes were characterized by means of nitrogen (N2) adsorption/desorption, and scanning electron microscopy/X-ray energy dispersive spectroscope (SEM-EDS). Experimental studies on Hg removal were investigated in both a fixed bed and an entrained flow reactor system. Petroleum coke activated carbon modified by NH4Br performs better mercury adsorption capacity than commonly used activated carbon from coal. It is noted that 1% additive of NH4Br into the petroleum coke activated carbon nearly remove all the mercury in a fixed bed within 120 min, and the mercury removal efficiency of entrained flow reactor system under condition of 120℃, 2 second residence time and about 90 000 C/Hg ratio is above 90%. The results solidly support that the modified high sulfur petroleum coke can be used as high effective mercury removal adsorbent in a flue gas injection of demercuration system for coal fired power plant.关键词
溴化铵/改性/高硫石油焦/活性炭/汞吸附Key words
ammonium bromide/modification/high sulfur petroleum coke/activated carbon/mercury adsorption分类
资源环境引用本文复制引用
洪亚光,段钰锋,朱纯,周强,佘敏,韦红旗..载溴高硫石油焦活性炭脱汞实验研究[J].中国电机工程学报,2014,(11):1762-1768,7.基金项目
国家自然科学基金(51076030,51376046)；江苏省环保科研课题基金(201113)；江苏省产学研联合创新资金(BY2013073-10)；煤燃烧国家重点实验室开放基金(FSKLCC1002)。Project Supported by National Natural Science Foundation of China (51076030,51376046) （51076030,51376046）
Jiangsu Province Environmental Protection Subject Foundation (201113) （201113）
Jiangsu Province United Creative Subject (BY2013073-10) （BY2013073-10）
Foundation of the State Key Laboratory of Coal Combustion (FSKLCC1002) （FSKLCC1002）
