中山大学学报(自然科学版)Issue(1):63-66,4.
新型光敏剂Corrole激发态动力学研究
The Studies on Ultrafast Dynamics of Three Kinds of Corroles
摘要
Abstract
The steady-state spectroscopy and the femtosceond fluorescence upconversion in three kinds of Ga Corroles in toluene and ethanol solvent have been studied.The results show that the effect of the hy-droxyl and PTZ substitution on the properties of those Corroles is not significant.In contrast,the blue shifts in absorption spectra,the red shifts in emission spectra and the reduction in fluorescence quantum yield observed when ethanol replaces toluene as a solvent.Moreover,the ultrafast dynamics S2→S1 of those Corroles varied significantly in different solvents.Evidently,solvent has a significant effect on those Corroles’ energy level structure and optical properties.关键词
Corrole/飞秒荧光上转换技术/超快动力学Key words
Corroles/femtosecond fluorescence upconversion technology/ultrafast dynamics分类
化学化工引用本文复制引用
王雪,封昌盛,何霜,史蕾,张蕾,刘海洋,王惠,计亮年..新型光敏剂Corrole激发态动力学研究[J].中山大学学报(自然科学版),2014,(1):63-66,4.基金项目
国家自然科学基金资助项目(61178037,11004256,21171057)、国家重点基础研究发展计划973资助项目(2013CB922403);中山大学光电材料与技术国家重点实验室开放课题资助项目 ()