安徽工程大学学报Issue(2)：34-37,4.
以1,2-双（4-吡啶基）乙烷为配体的铜（Ⅱ）配位聚合物的合成和晶体结构
Synthesis and crystal structure of copper coordination polymer constructed from 1,2-bis(4-pyridyl)ethane ligand
摘要
Abstract
Copper coordination polymer,[Cu2Cl2 (bpe)]n(1)(bpe=1,2-bis(4-pyridyl)ethane),has been synthesized by hydrothermal reactions,which have been structurally characterized by single-crystal X-ray diffraction,elemental analysis,IR spectra and power X-ray diffraction.The single crystal structure analy-sis reveals that the compound 1 crystallizes in the monoclinic system and space group P21/c with a=3.788 1(12),b=15.067(5),c=10.904(3)Å,β=96.460(4),V=618.4(3)Å3 ,Z=2,Dc=2.053 g/cm3 ,μ=3.849 mm-1 ,F(000)=380,R1=0.040 9,wR2= 0.099 9 [I>2σ(I)].X-ray diffraction analysis reveals that the copper ions and chlorine ions form one-dimensional ladder structure,which is further linked by bpe ligand and finally forms two-dimensional layered network.关键词
1,2-双(4-吡啶基)乙烷/配位聚合物/晶体结构Key words
1 ,2-bis(4-pyridyl)ethane/coordination polymer/crystal structure分类
化学化工引用本文复制引用
李勇,代佳佳,周卫祥,张坤,朱贤东..以1,2-双（4-吡啶基）乙烷为配体的铜（Ⅱ）配位聚合物的合成和晶体结构[J].安徽工程大学学报,2015,(2):34-37,4.基金项目
国家级大学生创新创业训练计划基金资助项目(201310363068) （201310363068）
