北京林业大学学报Issue(6):159-164,6.DOI:10.13332/j.cnki.jbfu.2014.06.003
脲醛树脂及三聚氰胺改性脲醛树脂对桉木热解液组分的影响
Effects of urea formaldehyde resin and melamine urea formaldehyde resin on eucalyptus pyrolysis liquid
摘要
Abstract
In order to effectively process wood-based panel waste by pyrolysis technology process, the effects of adhesives on wood pyrolysis liquid products was studied in this paper. GC/MS technique was used to analyze the pyrolysis liquids of eucalyptus, eucalyptus with 10% UF resin, eucalyptus with 10% MUF resin, UF resin and MUF resin. The results showed that the composition of eucalyptus pyrolysis liquid was complex, in which the relative content of 2,5-dimethylfuran reached 27. 54%, and that of 2-hydroxy-3-methyl-2-cyclopenten-1-one and 4-( 2-oxopropyl )-2-cyclohexen-1-one were 7. 03% and 7. 01%respectively, and 2,6-dimethoxy- phenol was 9. 47%. The relative amount of nitrogenous substance in the pyrolysis liquids of eucalyptus with UF resin was 22. 92% more than that in the pyrolysis liquid of eucalyptus wood. The pyrolysis liquid could be utilized in the production of fertilizer and soil amendment. The composition in the pyrolysis liquid of eucalyptus with MUF resin contained xylose and butyrrolactone which could not be detected in the pyrolysis liquid of eucalyptus. This study could provide theoretical foundation for utilization of the abandoned wood-based panel rationally.关键词
脲醛树脂/三聚氰胺改性脲醛树脂/热解/气质联用/桉木Key words
urea formaldehyde resin/melamine urea formaldehyde resin/pyrolysis/GC/MS/Eucalyptus分类
农业科技引用本文复制引用
张宇,母军,李思锦,赵阳..脲醛树脂及三聚氰胺改性脲醛树脂对桉木热解液组分的影响[J].北京林业大学学报,2014,(6):159-164,6.基金项目
国家自然科学基金项目(31170533)。 (31170533)