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新型硅烷复合物在铝材表面处理中的应用

葛圣松 张绘新 王俊祥 李孟龙

表面技术Issue(3):80-84,5.
表面技术Issue(3):80-84,5.

新型硅烷复合物在铝材表面处理中的应用

Study on Application of a New Silane Compound in the Treatment of Aluminum Surface

葛圣松 1张绘新 1王俊祥 1李孟龙1

作者信息

  • 1. 山东科技大学 化学与环境工程学院,青岛266590
  • 折叠

摘要

Abstract

Objective To develop a new silane compound which can replace the traditional chromate passivation solution in alu-minum surface treatment. Methods KH-560 and A-151 were compounded, and self-made waterborne polyester was added as hy-drolysis agent together with a crosslinking agent R carrying active groups. The effects of silane agent ratio, dosage of hydrolysis a-gent and crosslinking agent R on the stability of silane treatment agent and corrosion resistance of silane film were investigated. Results When the ratio of KH-560 and A-151 was 4:1, and the amount of hydrolysis agent was in the range of 0. 4% ~0. 6%, the storage time of treatment agent lasted more than 90 days, and the silane film had good corrosion resistance. For silane treatment a-gent with performance significantly decreased after long-time storage, demonstrable cross effect in silicon hydroxyl was formed through adding 4% crosslinking agent R, which could effectively enhance the protective properties of silane films. Conclusion The comprehensive properties of silane compound could meet the demands of industrial application, and the problems of environmental pollution by chromate passivation solution could be solved by the use of this new compound, which has good social benefits.

关键词

铝材/硅烷复合物/表面处理/水解促进剂/交联剂

Key words

aluminum/silane compound/surface treatment/hydrolytic agent/cross-linker

分类

矿业与冶金

引用本文复制引用

葛圣松,张绘新,王俊祥,李孟龙..新型硅烷复合物在铝材表面处理中的应用[J].表面技术,2014,(3):80-84,5.

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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