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双酚A型酚醛树脂改性双氰胺固化环氧树脂行为的研究

唐囡 杨又华 邓静伟 周建萍 刘志雷 刘光明

表面技术Issue(6):144-148,5.
表面技术Issue(6):144-148,5.

双酚A型酚醛树脂改性双氰胺固化环氧树脂行为的研究

Research on the Behavior of Dicyandiamide Modified by Bisphenol-A Type Phenolic Aldehyde Curing Epoxy Resin

唐囡 1杨又华 1邓静伟 1周建萍 2刘志雷 2刘光明2

作者信息

  • 1. 国网江西省电力科学研究院,南昌330096
  • 2. 南昌航空大学,南昌330063
  • 折叠

摘要

Abstract

ABSTRACT:Objective To obtain a latent, low-temperature and fast curing dicyandiamide agent. Methods A new latent curing agent of dicyandiamide modified by bisphenol A type phenolic aldehyde resin was synthesized and the structure was characterized by FTIR spectra. The impact of dicyandiamide dosage on product performance was investigated. The activity of the modified curing a-gent, the dosage and the curing temperature were studied with differential scanning calorimetry ( DSC) . Results The results showed that the suitable molar ratio of dicyandiamide and phenolic aldehyde was 0. 6 : 1, the optimal dosage of the modified curing agent was 30% ( relative to the epoxy resin mass fraction) , and the constant curing temperature after modification was 127 ℃. Conclu-sions The resulting curing agent of bisphenol A phenolic resin modified dicyandiamide exhibited the best comprehensive perform-ances.

关键词

酚醛/双氰胺/潜伏固化剂/改性

Key words

phenolic aldehyde/dicyandiamide/latent curing agent/modification

分类

化学化工

引用本文复制引用

唐囡,杨又华,邓静伟,周建萍,刘志雷,刘光明..双酚A型酚醛树脂改性双氰胺固化环氧树脂行为的研究[J].表面技术,2014,(6):144-148,5.

基金项目

国家电网公司科技项目(521820130014)Fund:Supported by State Grid Practical Project(521820130014) (521820130014)

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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