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氮掺杂石墨烯柔性薄膜的制备及其超电容性能

钟奇能 粟泽龙 李新禄

表面技术Issue(1):51-55,63,6.
表面技术Issue(1):51-55,63,6.

氮掺杂石墨烯柔性薄膜的制备及其超电容性能

Preparation and Supercapacitor Performance of a Flexible Nitrogen-doped Graphene Film

钟奇能 1粟泽龙 1李新禄1

作者信息

  • 1. 重庆大学 材料科学与工程学院,重庆400030
  • 折叠

摘要

Abstract

ABSTRACT:Objective To improve the electrochemical performance of graphene films for supercapacitors. Methods Flexible ni-trogen-doped graphene ( N-doped graphene) films with porous structure were synthesized by hydrothermal and pyrolysis methods. The structure of the N-doped graphene films were analyzed by scanning electron microscope ( SEM) , X-ray diffraction ( XRD) and isotherms. The electrochemical capacitance of N-doped graphene films was examined by three-electrode system test cyclic voltam-metry and galvanostatic charge-discharge methods. Results The experiments indicated that the flexible N-doped graphene films re-tained the folded and transparent characteristics of graphene oxide, and formed a three-dimensional porous structure as well. The surface area of N-doped grapheme was measured to be 280. 78 m2/g by the nitrogen adsorption-desorption test. The specific dis-charge capacitance for the material was 169 F/g in 1. 0 mol/L NaSO4 solution when the current density was 0. 1 A/g. Conclusion The doping of nitrogen atoms and the porous structure of the flexible N-doped graphene films could effectively improve the superca-pacitor performance of the graphene material.

关键词

氮掺杂石墨烯/多孔结构/超级电容器

Key words

N-doped graphene/porous structure/supercapacitor

分类

化学化工

引用本文复制引用

钟奇能,粟泽龙,李新禄..氮掺杂石墨烯柔性薄膜的制备及其超电容性能[J].表面技术,2015,(1):51-55,63,6.

基金项目

国家自然科学基金(51172293) (51172293)

中央高校基础研究基金(CDJZR13130027)Fund:Supported by the National Natural Science Foundation of China (51172293) and Fundamental Research Funds for the Central Universities (CDJZR13130027) (CDJZR13130027)

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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