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界面热力学在Sn晶须生长研究中的应用

林冰 黄琳 简玮 王江涌

表面技术Issue(2):1-7,18,8.
表面技术Issue(2):1-7,18,8.DOI:10.16490/j.cnki.issn.1001-3660.2015.02.001

界面热力学在Sn晶须生长研究中的应用

Application of Interface Thermodynamics in Study on Sn Whisker Growth

林冰 1黄琳 1简玮 1王江涌1

作者信息

  • 1. 汕头大学 理学院,广东 汕头515063
  • 折叠

摘要

Abstract

Objective To investigate the thermodynamic mechanisms of the intermetallic compound ( IMC ) formation and Sn whisker growth in Sn-Cu bilayer thin film system. Methods Using the interface thermodynamics theory, the IMC formation and the Sn whisker growth were studied through calculating the corresponding surface energies, interface energies and critical thickness. Results The IMC Cu6 Sn5 was firstly formed at the triple junction of Sn grain boundary and Sn/Cu interface and then grew along the Sn/Cu interface. The resulting stress gradient drove the diffusion of Sn atoms to the surface and formed Sn whisker on it. Conclu-sion The Sn whisker growth was caused by the IMC formation in Sn sublayer, based on which some methods were proposed for in-hibiting the growth of Sn whisker.

关键词

界面热力学/金属间化合物相/Sn晶须/生长机制

Key words

interface thermodynamics/intermetallic compound phase/Sn whisker/growth mechanism

分类

矿业与冶金

引用本文复制引用

林冰,黄琳,简玮,王江涌..界面热力学在Sn晶须生长研究中的应用[J].表面技术,2015,(2):1-7,18,8.

基金项目

国家自然科学基金(11274218) Fund:Supported by the National Natural Science Foundation of China (11274218) (11274218)

表面技术

OA北大核心CSCDCSTPCD

1001-3660

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