波谱学杂志Issue(3)：331-340,10.
铜丝光沸石上甲醇羰基化反应的固体核磁共振研究
Carbonylation of Methanol on Cu-H-MOR Zeolites:Insights from Solid-State NMR Spectroscopy
摘要
Abstract
Carbonylation of methanol with CO on Cu-H-mordenite (Cu-H-MOR) zeolites was studied by 13C solid-state NMR spectroscopy. By characterizing the interaction between adsorbed species and Cu2+ cations, we determined copper methoxy group (Cu-OCH3) and copper acetyl group (Cu-(CO)-CH3) as the intermediates of this reaction. The possible mechanisms of carbonylation reaction of methanol with CO on Cu-H-MOR zeolites were discussed.关键词
固体核磁共振(solid-state NMR)/丝光沸石/羰基化反应/多相催化/反应机理Key words
solid-state NMR spectroscopy/mordenite zeolite/carbonylation reaction/heterogeneous catalysis/reaction mechanism分类
数理科学引用本文复制引用
李博解,徐君,王强,王秀梅,齐国栋,邓风..铜丝光沸石上甲醇羰基化反应的固体核磁共振研究[J].波谱学杂志,2014,(3):331-340,10.基金项目
国家自然科学基金资助项目(21210005，21173254，21221064)；武汉市晨光计划资助项目(201271031383)． （21210005，21173254，21221064）
