波谱学杂志Issue(1)：87-94,8.DOI:10.11938/cjmr20150110
D-樟脑与β-环糊精包合物的结构表征
Structural Elucidation of D-Camphor andβ-Cyclodextrin Inclusion Complex
朱庆英 1何佩芝1
作者信息
- 1. 惠州学院 化学工程系，广东 惠州 516007
- 折叠
摘要
Abstract
Inclusion complex ofβ-cyclodextrin (β-CD) and D-camphor was prepared from saturated solution with stirring. The stoichiometric ratio of the inclusion complex was found to be 1∶1, as indicated by the 1H NMR results. XRD and FTIR spectroscopy was used to probe the intermolecular interactions between D-camphor and β-CD. 1H ROESY NMR results showed that the bicyclo[2.2.1]-2-heptanone of D-camphor was located in the cavity ofβ-CD, and its methyl group was partially outside. Quantum chemical calculation was used to obtain minimized binding energy and optimized structure, suggesting the presence of hydrogen bonding.关键词
核磁共振(NMR)/包合物/β-环糊精(β-CD)/D-樟脑Key words
NMR/inclusion complex/β-cyclodextrin/D-camphor分类
化学化工引用本文复制引用
朱庆英,何佩芝..D-樟脑与β-环糊精包合物的结构表征[J].波谱学杂志,2015,(1):87-94,8.
