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立方锡酸镁/氧化锡复合氧化物的合成及其气敏性能

崔宇 覃愿 张为海 刘雷 熊娟

传感技术学报Issue(7):857-860,4.
传感技术学报Issue(7):857-860,4.DOI:10.3969/j.issn.1004-1699.2014.07.001

立方锡酸镁/氧化锡复合氧化物的合成及其气敏性能

Synthesis and Gas Sensing Properties of Cubic Mg2 SnO4/SnO2 Complex Oxides

崔宇 1覃愿 1张为海 1刘雷 1熊娟1

作者信息

  • 1. 湖北大学物理与电子科学学院,武汉430062
  • 折叠

摘要

Abstract

Precursor MgSn( OH) 6 was synthesized by the hydrothermal method. And Mg2 SnO4/SnO2 complex oxide cubic nanoparticles were obtained by subsequent thermal treatment. The phase structures,surface morphologies and component of the samples were characterized by X-ray diffraction,scanning electron microscope and energy disperse spectroscopy. The gas sensitivity and selectivity of the complex oxide for methanol has been studied at different working temperature. The results show that the Mg2 SnO4/SnO2 exhibited good sensitivity and selectivity. It exhibits a linear relationship in the range of 50×10-6 ~5 000×10-6 at the optimum temperature of 300 ℃. The response and recovery time of the gas sensor were 12s and 8s,respectively,for 2 000×10-6 methanol.

关键词

锡酸镁/二氧化锡/复合氧化物/气敏性能/立方纳米颗粒

Key words

Mg2 SnO4/SnO2/complex oxides/gas sensing properties/cubic nanoparticles

分类

信息技术与安全科学

引用本文复制引用

崔宇,覃愿,张为海,刘雷,熊娟..立方锡酸镁/氧化锡复合氧化物的合成及其气敏性能[J].传感技术学报,2014,(7):857-860,4.

基金项目

国家自然科学基金项目(61106067) ()

湖北省科技厅重点项目(2013CFA043) ()

传感技术学报

OA北大核心CSCDCSTPCD

1004-1699

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