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几种LiFePO4正极材料的表征及电化学性能研究

湛赏 邱景义 余仲宝 宋世栋

电源技术Issue(4):732-735,4.
电源技术Issue(4):732-735,4.

几种LiFePO4正极材料的表征及电化学性能研究

Characterizing and study on electrochemical performance of LiFePO4 cathode materials

湛赏 1邱景义 2余仲宝 2宋世栋1

作者信息

  • 1. 中国矿业大学化学与环境工程学院,北京100083
  • 2. 防化研究院军用化学电源研究与发展中心,北京100191
  • 折叠

摘要

Abstract

The crystal inity, morphology, particle size and electrochemical performance of three kinds of LiFePO4 provided by three manufacturers were characterized by XRD, SEM, CV, EIS and constant current charge/discharge. The results show that these properties have great influences on the discharge capacity, cycle life and rate property of the batteries. Sample 1 has perfect crystal inity, and the secondary particle aggregated with nanoscale initial particles has proper size. Accordingly, 18650-type battery using sample 1 as the cathode material exhibits the highest specific capacity, the best cycle stability and the highest capacity retention when discharging at 8 .

关键词

锂离子电池/LiFePO4/电化学性能/物化性质

Key words

lithium-ion battery/LiFePO4/electrochemical performance/physical-chemical property

分类

信息技术与安全科学

引用本文复制引用

湛赏,邱景义,余仲宝,宋世栋..几种LiFePO4正极材料的表征及电化学性能研究[J].电源技术,2015,(4):732-735,4.

基金项目

国家“863”现代交通技术领域 ()

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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