东南大学学报（自然科学版）Issue(3)：605-609,5.DOI:10.3969/j.issn.1001-0505.2014.03.027
污泥残炭对城市污泥催化热解制油影响的实验研究
Experimental study on bio-oil obtained from municipal sludge pyrolysis catalyzed by char
摘要
Abstract
Pyrolysis of municipal sludge catalyzed by residue char was conducted in order to research the influences of the temperature and the proportion of char on the product yield and the component of the organic phase (OP).The results show that for non-catalytic pyrolysis,the yield of OP rea-ches a maximum of 6.83% at 500 ℃.Residue char is benifical to the removal of volatiles.Char benefits the hydrodeoxygenation and removal of chlorinated compounds,while it is negative to the reduction of PAHs (polycyclic aromatic hydrocarbons).Residue char was also treated with support-ing Fe,Cu,Al and Ni to study the catalytic effect of treated char.The results show that char sup-ported with Al favors the enhancement of HHV (higher heating value)and reduction of viscosity of OP.The contents of oxygenated compounds and nitrogen compounds decrease.The char supported with Fe is the best for hydrodeoxygenation and the reduction of viscosity of OP.Compared with the original carbon residue,the viscosity of OP catalyzed by char supported with Fe reduces by 24.32%while the content of hydrocarbons increases by 17.62%.Char supported with Ni helps decrease ni-trogen compounds.PAHs are not found in the OP catalyzed by char supported with Cu.关键词
城市污泥/残炭/催化热解/有机相Key words
municipal sludge/residue char/catalytic pyrolysis/organic phase分类
资源环境引用本文复制引用
张亚,金保癉,左武,孙宇..污泥残炭对城市污泥催化热解制油影响的实验研究[J].东南大学学报（自然科学版）,2014,(3):605-609,5.基金项目
高等学校博士学科点专项科研基金资助项目（201109213DD01）、中央高校基本料研业务费专项资金资助项目、江苏省科技厅前瞻性研究资助项目（BY20111149）． （）
