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YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程

张继森 张立国 任建岳 段佩华 骆永石 吕少哲

发光学报Issue(3):262-266,5.
发光学报Issue(3):262-266,5.DOI:10.3788/fgxb20153603.0262

YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程

Properties of NIR Emissions with Energy-transfer Processes in Cr3+-and Yb3+-doped Y3 Al5 O12 Powder Materials

张继森 1张立国 1任建岳 1段佩华 1骆永石 1吕少哲1

作者信息

  • 1. 中国科学院 长春光学精密机械与物理研究所,吉林 长春 130033
  • 折叠

摘要

Abstract

Cr3+-and Yb3+-doped YAG powder samples were prepared and the energy transfer ( ET) mechanism in the samples was evaluated by the photoluminescence ( PL) , photoluminescence exci-tation ( PLE) and light-emitting lifetime. By taking advantage of the spin allowed 4 A2→ 4 T2 and 4 A2→ 4 T1 absorption of Cr3+ and the efficient energy transfer from Cr3+ to Yb3+, the broadband spectral conversion makes Yb3+:2 F5/2→2 F7/2 transition give off a desirable emission around 1 000 nm, which is according to the maximum spectral response of c-Si solar cells, and hence would lead to the enhancement of silicon solar photovoltaic conversion efficiency.

关键词

Cr3+/Yb3+/近红外发光/能量传递

Key words

Cr3+/Yb3+/NIR emission/energy transfer

分类

数理科学

引用本文复制引用

张继森,张立国,任建岳,段佩华,骆永石,吕少哲..YAG中Cr3+和Yb3+的发光特征以及Cr3+和Yb3+之间的能量传递过程[J].发光学报,2015,(3):262-266,5.

基金项目

国家自然科学基金(11174276,11174278)资助项目 (11174276,11174278)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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