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GdBO3:Pr3+,Yb3+中Pr3+到Yb3+的能量传递及发光性质

朱凡 由芳田 时秋峰 彭洪尚 黄世华

发光学报Issue(7):751-756,6.
发光学报Issue(7):751-756,6.DOI:10.3788/fgxb20153607.0751

GdBO3:Pr3+,Yb3+中Pr3+到Yb3+的能量传递及发光性质

Luminescence Properties and Energy Transferfrom Pr3 +to Yb3+in GdBO3:Pr3+,Yb3+

朱凡 1由芳田 1时秋峰 1彭洪尚 1黄世华1

作者信息

  • 1. 发光与光信息教育部重点实验室 北京交通大学光电子技术研究所,北京 100044
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摘要

Abstract

GdBO3∶Pr3+ and GdBO3∶Pr3+, Yb3+ samples were prepared by solid state reaction at high temperature. XRD patterns, excitation spectra and emission spectra in the Vis-NIR range of the obtained samples were studied in detail at room temperature. The emission of 2 F5/2→2 F7/2 (980 nm) of Yb3+ was observed under 446 nm excitation, indicating the occurrence of the energy transfer from Pr3+ to Yb3+. The fluorescence intensities varied with different Yb3+doping concentrations. Lumi-nescence decay curves of Pr3+:3 P0 level were recorded as a function of the Yb3+ concentrations and energy transfer efficiency was also calculated. Based on Inokuti-Hirayama model, the energy transfer type from Pr3+ to Yb3+was derived to be electric dipole-dipole interaction.

关键词

近红外发光/能量传递/稀土离子/GdBO3

Key words

near infrared/energy transfer/rare earth ions/GdBO3

分类

数理科学

引用本文复制引用

朱凡,由芳田,时秋峰,彭洪尚,黄世华..GdBO3:Pr3+,Yb3+中Pr3+到Yb3+的能量传递及发光性质[J].发光学报,2015,(7):751-756,6.

基金项目

国家自然科学基金(11274038)资助项目 (11274038)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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