辽宁石油化工大学学报Issue(3)：20-22,39,4.DOI:10.3696/j.issn.1672-6952.2015.03.005
单质合成碘化亚铜及其催化性能研究
Study of Catalytic Activity and Synthesis of Copper(I)Iodide by an Elemental Reaction
摘要
Abstract
CuI was fabricated by an element-direct-reaction route at 40 ℃ in ethylene glycol as solvent,copper powder as oxidant,iodine as reducing agent.The product was characterised by X-ray diffraction (XRD)and scanning electron microscopy (SEM).The catalytic activity was reviewed as a catalyst in the thermal decomposition of ammonium perchlorate.The result show that CuI nanoparticles is sheet strcture,its average diameter is about 99 nm at 40 ℃ and its average diameter is about 87 nm at 60 ℃.Addition of CuI in ammonium perchlorate (AP)led to a significant reduction of low decomposition temperature and high decomposition temperature of AP,two decomposition temperture peaks incorporate a decomposition temperture peak, and the temperature of the peak at the high decomposition temperature stage is therefore decreased by 1 1 1 ℃.关键词
单质反应/碘化亚铜/高氯酸铵/纳米材料/催化分解Key words
An elemental reaction/Copper(Ⅰ)iodide/Ammonium perchlorate/Nanometer material/Catalytic decomposition分类
化学化工引用本文复制引用
赵佳琪,赖君玲,罗根祥..单质合成碘化亚铜及其催化性能研究[J].辽宁石油化工大学学报,2015,(3):20-22,39,4.基金项目
全国大学生创新创业训练计划项目(201310148007)。 （201310148007）
