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基于高荧光碳纳米粒子的Fe3+超灵敏检测

尹苹苹 艾可龙 李美丽 孙国英

分析化学Issue(10):1427-1433,7.
分析化学Issue(10):1427-1433,7.DOI:10.11895/j.issn.0253-3820.140218

基于高荧光碳纳米粒子的Fe3+超灵敏检测

Highly Fluorescent Carbon Nanoparticles for Sensitive Detection of IronⅢ

尹苹苹 1艾可龙 2李美丽 1孙国英1

作者信息

  • 1. 长春工业大学化学与生命科学学院,长春130012
  • 2. 中国科学院长春应用化学研究所电分析化学国家重点实验室,长春130022
  • 折叠

摘要

Abstract

A simple preparative strategy was proposed for the preparation of water-soluble, bright blue-emitting carbon nanoparticles ( CNPs ) at different temperatures by hydrothermal treatment using bean curd residue as carbon source for the first time. When the temperature reaches 240 ℃, quantum yield ( QY) can be up to 15. 24%. Most importantly, such fluorescent CNPs can be served as an effective sensing platform for label-free sensitive and selective detection of Fe3+ions with a detection of limit as low as 50 nmol/L, which is nearly 2 orders of magnitude lower than the maximum level of Fe3+ions in the drinking water permitted by the European Community. These outstanding properties give promising potential for reliable detection of Fe3+ in intracellular fluid and water samples, even bioimaging and optical imaging without being hazard in the future.

关键词

豆腐残渣/碳纳米粒子/荧光探针/铁离子

Key words

Bean curd residue/Carbon nanoparticles/Fluorescence probe/Iron(Ⅲ)

引用本文复制引用

尹苹苹,艾可龙,李美丽,孙国英..基于高荧光碳纳米粒子的Fe3+超灵敏检测[J].分析化学,2014,(10):1427-1433,7.

基金项目

本文系国家自然科学基金青年基金(No.21003013)及吉林省科技厅自然科学基金(No.201215126)资助 (No.21003013)

分析化学

OA北大核心CSCDCSTPCDSCI

0253-3820

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