高等学校化学学报Issue(5)：1016-1022,7.DOI:10.7503/cjcu20131301
一步溶剂热法合成C掺杂介孔TiO2可见光光催化材料
Synthesis of Carbon-doped Mesoporous TiO2 Visible-light Photocatalytic Materials via One Pot Solvothermal Method
摘要
Abstract
C doped TiO2 mesoporous materials with spherical morphology were synthesized via solvothermal method in ethanol, using tetrabutyl titanate( TBOT) as the titanium source under template-free condition. The synthesized samples were characterized by XRD, SEM, TEM, N2 adsorption-desorption, XPS, UV-Vis, and photocatalytic degradation of RhB. The results indicated that, the synthesized samples were pure phase anatase TiO2 , and they had morphology of uniform size spheres with the accumulation of the nanoparticles. The crystallinity and morphology of the synthesized samples could be regulated by the volume of adding acetic acid during the synthesis process. The results showed trace of C atoms getting into TiO2 crystal lattice, replacing the position of O atoms, narrowing the band gap of TiO2 , and leading to the enhancement of visible light absorption. Photocatalytic test confirmed its excellent adsorption property and photocatalytic activity under visible light, which have very important meaning for solving environmental problems in current society.关键词
C掺杂TiO2/介孔材料/可见光催化材料/一步溶剂热法Key words
C doped TiO2/Mesoporous material/Visible-light photocatalytic material/One pot solvothermal method分类
化学化工引用本文复制引用
丁双,朱国巍,王润伟,张宗弢,裘式纶..一步溶剂热法合成C掺杂介孔TiO2可见光光催化材料[J].高等学校化学学报,2014,(5):1016-1022,7.基金项目
国家自然科学基金(批准号:20971052,20770141,201201145)资助.@@@@ Supported by the National Natural Science Foundation of China(Nos.20971052,20770141,201201145) （批准号:20971052,20770141,201201145）
