高等学校化学学报Issue(5)：1111-1118,8.DOI:10.7503/cjcu20130840
一锅法制备pH响应性聚丙烯酰基乙二胺盐酸盐-卟啉/芴荧光聚合物
Preparation of pH-Sensitive Fluorescent Poly(acryl-2-aminoethy- lammonium hydrochloride) with Porphyrin or Fluorene by One-pot Method
摘要
Abstract
Poly ( N-tert-butoxycarbonyl-N’-acryloyl-1 , 2-diaminoethane ) ( PBAEN ) with dithioester as end groups was prepared via reversible addition-fragmentation chain transfer polymerization(RAFT). The one-pot method, which the reduction of dithioester and Click reaction between thiol and epoxy group were conducted simultaneously, was used to prepared fluorescently label poly( N-acryloyl-1,2-diaminoethane hydrochloride)-porphyrin(PAEN-EPT) and poly(N-acryloyl-1,2-diaminoethane hydrochloride)-fluorene(PAEN-DEPF). The fluorescence intensity of PAEN-EPT and PAEN-DEPF in aqueous solution decreased dramatically as pH≥7 due to the polymer chain shrinking. The PAEN-EPT and PAEN-DEPF showed the pH-response. In addition, the quantum yield for PAEN-EPT aqueous solution could reach 0. 096.关键词
水溶性/荧光聚合物/可逆加成-断裂链转移聚合法/点击反应/一锅法Key words
Water-soluble/Fluorescent polymer/Reversible addition-fragmentation chain transfer ( RAFT ) polymerization/Click reaction/One-pot method分类
化学化工引用本文复制引用
刘楠,武永刚,白利斌,王园,黄海潮,赵洪池,巴信武..一锅法制备pH响应性聚丙烯酰基乙二胺盐酸盐-卟啉/芴荧光聚合物[J].高等学校化学学报,2014,(5):1111-1118,8.基金项目
国家自然科学基金(批准号:21274037)、河北省自然科学基金(批准号：B2013201174)和河北省教育厅基金(批准号:2010015)资助.@@@@ Supported by the National Natural Science Foundation of China(No.21274037), the Natural Science Foundation of Hebei Province, China (No. B2013201174) and the Foundation of Hebei Education Department, China(No.2010015) （批准号:21274037）
