高等学校化学学报Issue(6)：1307-1310,4.DOI:10.7503/cjcu20131218
介孔 TiO2担载 Cu（OH）2及其催化炔烃氧化偶联反应
Mesoporous Titania Supported Copper Hydroxide as an Efficient Heterogeneous Catalyst in Oxidative Homocoupling of Alkynes
摘要
Abstract
Ordered mesoporous titania supported copper hydroxide was used as catalysts in heterogeneous oxi-dative homocoupling of alkynes(Glaser reaction). The results showed high catalytic performance. Highly dis-persed copper hydroxide was regarded as the active site and mesoporous structure of TiO2 benefit the high dis-persion of active sites as well as the diffusion of the reactants and products in the reactions. 1,3-Dyne deriva-tive, the products of Glaser reaction, is an important class of compounds in chemistry and materials science. Thus, Cu(OH) 2 / TiO2 is of great importance in the industrial application.关键词
有序介孔 TiO2/氢氧化铜/Glaser 反应/炔烃氧化偶联/多相催化Key words
Ordered mesoporous titania/Cu(OH) 2/Glaser reaction/Heterogeneous oxidative homocoupling of alkynes/Heterogeneous catalysis分类
化学化工引用本文复制引用
张海鹏,潘庆芝,邹永存..介孔 TiO2担载 Cu（OH）2及其催化炔烃氧化偶联反应[J].高等学校化学学报,2014,(6):1307-1310,4.基金项目
国家自然科学基金(批准号:21371070)和吉林省科技发展计划项目(批准号:20140101041JC,20130204001GX)资助. Supported by the National Natural Science Foundation of China(No.21371070) and the Science and Technology Development Program of Jilin Province, China(Nos.20140101041JC,20130204001GX) （批准号:21371070）
