高等学校化学学报Issue(6)：1330-1335,6.DOI:10.7503/cjcu20140113
聚氧乙烯醚型表面活性剂的合成及表面性质
Surface and Interfacial Properties of Polyoxyethylene Ether-type Surfactants
摘要
Abstract
A series of poly nonylphenol polyoxyethylene ether nonionic surfactants with different polymeriza-tion degerees was synthesized with nonyl phenol and formaldehyde. The structures were characterized by infra-red spectroscopy and nuclear magnetic resonance. Moreover, the surface properties were evaluated using the surface tension method. It is found that critical micelle concentration(cmc) of monomer, dimer and trimer in-cease with increasing of the number of hydrophilic group epoxyethane(EO) of the surfactants. In the case of the same number of EO, the cmc of surfactants were significantly reduce with the increase of the degree of polymerization. Although dimer and trimer show good surface properties, the surface property of trimer is more excellent than dimer. Moreover, dimer and trimer show more excellent adsorption and dispersion performance because the arrangments of them on the air/ water boundary are significantly more compacted than dimer.关键词
聚壬基酚聚氧乙烯醚表面活性剂/临界胶束浓度/表面张力Key words
Polyoxyethylene ether surfactant/Critical micelle concentration/Surface tension分类
化学化工引用本文复制引用
黄海龙,李红玉,张雷,任天瑞..聚氧乙烯醚型表面活性剂的合成及表面性质[J].高等学校化学学报,2014,(6):1330-1335,6.基金项目
国家“八六三”计划项目(批准号:2011AA100503)和国家自然科学基金(批准号:21172147)资助. Supported by the National High Technology Research and Development Program of China(No.2011AA1005003) and the National Natural Science Foundation of China(No.21172147) （批准号:2011AA100503）
