高等学校化学学报Issue(8)：1629-1634,6.DOI:10.7503/cjcu20131282
三环己基锡邻（二茂铁甲酰基）苯甲酸酯配位聚合物的微波固相合成、晶体结构及性能
Microwave Assisted Solid-state Synthesis, Crystal Structure, Properties of the Coordination Polymer Constructed from Tricyclohexyltin Hydroxide and o-Ferrocenylcarbonyl Benzoic Acid
摘要
Abstract
A novel coordination polymer tricyclohexyltin ( o-ferrocenylcarbonyl ) benzoate was synthesized by the reaction of tricyclohexyltin hydroxide with o-ferrocenylcarbonyl benzoic acid under microwave irradiation. It was characterized by UV, IR, 1 H and 13 CNMR, elemental analysis and X-ray crystal diffraction. The crys-tal structure shows a distorted trigonal bipyramidal configuration with five-coordination for the central tin atom. The tin atoms and the oxygen atoms of C( O)-O and CO from the o-ferrocenylcarbonyl benzoate are interconnected to form a one-dimensional coordination polymer chain. The thermal studies showed that com-plex exhibited higher thermal stability. Electrochemical studies of the complex have been made in EtOH/H2 O by cyclic voltammetry. The complex shows quasi reversible electron transfer process. The in vitro antitumour activity of the complex was tested. The results show that the complex exhibits better antitumour activity in vitro against HT-29, MCF-7, HepG2, KB and A549 tumour cells. So the complex may have potential applications.关键词
配位聚合物/晶体结构/电化学性质/热稳定性/抗癌活性Key words
Coordination polymer/Crystal structure/Electrochemical property/Thermal stability/Anticancer activity分类
化学化工引用本文复制引用
邝代治,冯泳兰,庾江喜,张复兴,蒋伍玖,彭雁,朱小明,谭宇星..三环己基锡邻（二茂铁甲酰基）苯甲酸酯配位聚合物的微波固相合成、晶体结构及性能[J].高等学校化学学报,2014,(8):1629-1634,6.基金项目
湖南省自然科学基金(批准号:13JJ3112)、湖南省科技计划(批准号:2013TZ2025)、湖南省高校创新平台开放基金(批准号:13K105,12K124)、衡阳市科技计划(批准号:2012KJ30)、衡阳师范学院协同创新中心培育项目(批准号:12XT02)和青年骨干教师培养计划(2012)资助.Supported by the Hunan Provincial Natural Science Foundation of China(No.13JJ3112), the Scientific&Technological Projects of Hunan Province, China(No.2013TZ2025), the Open Fund Based on Innovation Platform of Hunan Universities, China(Nos.13K105,12K124), the Scientific &Technological Projects of Hengyang City, China(No.2012KJ30), the Cultivation Projects Based on Collaborative Innovation Center of Hengyang Normal University, China(No.12XT02) and the Youth Backbone Teacher Training Program of Hengyang Normal University, China (No.2012) （批准号:13JJ3112）
