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由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用

孟宪斌 高秋明

高等学校化学学报Issue(8):1715-1719,5.
高等学校化学学报Issue(8):1715-1719,5.DOI:10.7503/cjcu20140351

由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用

Porous Carbon from Carbonized Metal-organic Frameworks for Lithium Sulphur Batteries

孟宪斌 1高秋明1

作者信息

  • 1. 北京航空航天大学化学与环境学院,北京100191
  • 折叠

摘要

Abstract

An aluminum metal-organic framework ( MOF ) was prepared by hydrothermal method. Porous carbon was produced by direct carbonization of MOFs and then was loaded with sulfur. XRD patterns show that the porous carbon is partially graphitized during the high temperature carbonization. N2 sorption isotherms illustrate that the porous carbon contain both microporous and mesoporous structures. Charge-discharge tests were carried out among hierarchically sulfur loading lithium sulfur batteries. The initial discharge capacity of S/C-46. 3 sample is 1272 mA·h/g at 0.01 C and 934 mA·h/g at 0.1 C with good cycle performance.

关键词

金属有机骨架/多孔碳/正极材料/锂硫电池

Key words

Metal-organic framework/Porous carbon/Cathode material/Lithium sulphur battery

分类

化学化工

引用本文复制引用

孟宪斌,高秋明..由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用[J].高等学校化学学报,2014,(8):1715-1719,5.

基金项目

国家自然科学基金(批准号:U0734002)、国家“九七三”计划项目(批准号:2011CB935700,2014CB931800)和中国航空基金(批准号:2013ZF51069)资助.覮 Supported by the National Natural Science Foundation of China(No. U0734002), the National Basic Research Programs of China(Nos.2011CB935700,2014CB931800) and the Chinese Aeronautic Project(No.2013ZF51069) (批准号:U0734002)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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