高等学校化学学报Issue(8):1715-1719,5.DOI:10.7503/cjcu20140351
由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用
Porous Carbon from Carbonized Metal-organic Frameworks for Lithium Sulphur Batteries
摘要
Abstract
An aluminum metal-organic framework ( MOF ) was prepared by hydrothermal method. Porous carbon was produced by direct carbonization of MOFs and then was loaded with sulfur. XRD patterns show that the porous carbon is partially graphitized during the high temperature carbonization. N2 sorption isotherms illustrate that the porous carbon contain both microporous and mesoporous structures. Charge-discharge tests were carried out among hierarchically sulfur loading lithium sulfur batteries. The initial discharge capacity of S/C-46. 3 sample is 1272 mA·h/g at 0.01 C and 934 mA·h/g at 0.1 C with good cycle performance.关键词
金属有机骨架/多孔碳/正极材料/锂硫电池Key words
Metal-organic framework/Porous carbon/Cathode material/Lithium sulphur battery分类
化学化工引用本文复制引用
孟宪斌,高秋明..由含铝金属有机骨架材料制备的多孔碳在锂硫电池中的应用[J].高等学校化学学报,2014,(8):1715-1719,5.基金项目
国家自然科学基金(批准号:U0734002)、国家“九七三”计划项目(批准号:2011CB935700,2014CB931800)和中国航空基金(批准号:2013ZF51069)资助.覮 Supported by the National Natural Science Foundation of China(No. U0734002), the National Basic Research Programs of China(Nos.2011CB935700,2014CB931800) and the Chinese Aeronautic Project(No.2013ZF51069) (批准号:U0734002)