高等学校化学学报Issue(1):55-60,6.
柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征
Farbrication and Characterization of Flexible, Transparent and Self-standing Sb Doped SnO2 Electrospun Nanofiber Films†
摘要
Abstract
Flexible, transparent and selfstanding Sb doped SnO2 ( ATO) nanofiber films were successfully fabricated by means of a lowcost and scalable electrospinning process, with tin tetrachloride and antimony tri chloride as precursors. The asprepared ATO nanofiber films are typical interconnected nanofiber networks and show a single SnO2 rutile crystal structures. With increasing the calcination temperature from 520 ℃ to 700℃, the average diameter of ATO nanofibers decrease from 200 nm to 150 nm, but accompanied by an increase in the average diameter of ATO nanoparticles. Meanwhile, the transmittance of the ATO nanofiber film increa ses from 72% to 80%, while their resistance decreases from 5. 23 Ω·cm to 2. 20 Ω·cm. Importantly, after 500 cycles of bending, the selfstanding ATO nanofibers show no obvious electrical degradation. The ATO nanofiber films show promise for application in many fields, such as flexible liquid crystal displays, solar cells and flexible and transparent functional electronics.关键词
静电纺丝/氯化锡锑纳米纤维/自支撑/柔性导电膜Key words
Electrospinning/Sb Doped SnO2( ATO) nanofiber/Selfstanding/Flexible conducting film分类
化学化工引用本文复制引用
孔壮,李勇,鹿现永,朱英,江雷..柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征[J].高等学校化学学报,2015,(1):55-60,6.基金项目
国家“八六三”计划项目(批准号:2012AA030305)、国家“九七三”计划项目(批准号:2012CB933200)和国家自然科学基金(批准号:51273008,51473008)资助.? Supported by the National High Technology Research and Development Program of China(No.2012AA030305), the National Basic Research Program of China(No.2012CB933200) and the National Natural Seience Foundation of China(Nos.51273008,51473008) (批准号:2012AA030305)