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首页|期刊导航|高等学校化学学报|柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征

柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征

孔壮 李勇 鹿现永 朱英 江雷

高等学校化学学报Issue(1):55-60,6.
高等学校化学学报Issue(1):55-60,6.

柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征

Farbrication and Characterization of Flexible, Transparent and Self-standing Sb Doped SnO2 Electrospun Nanofiber Films†

孔壮 1李勇 1鹿现永 1朱英 1江雷1

作者信息

  • 1. 北京航空航天大学仿生界面科学与技术教育部重点实验室,化学与环境学院,北京100191
  • 折叠

摘要

Abstract

Flexible, transparent and self­standing Sb doped SnO2 ( ATO) nanofiber films were successfully fabricated by means of a low­cost and scalable electrospinning process, with tin tetrachloride and antimony tri­ chloride as precursors. The as­prepared ATO nanofiber films are typical interconnected nanofiber networks and show a single SnO2 rutile crystal structures. With increasing the calcination temperature from 520 ℃ to 700℃, the average diameter of ATO nanofibers decrease from 200 nm to 150 nm, but accompanied by an increase in the average diameter of ATO nanoparticles. Meanwhile, the transmittance of the ATO nanofiber film increa­ ses from 72% to 80%, while their resistance decreases from 5. 23 Ω·cm to 2. 20 Ω·cm. Importantly, after 500 cycles of bending, the self­standing ATO nanofibers show no obvious electrical degradation. The ATO nanofiber films show promise for application in many fields, such as flexible liquid crystal displays, solar cells and flexible and transparent functional electronics.

关键词

静电纺丝/氯化锡锑纳米纤维/自支撑/柔性导电膜

Key words

Electrospinning/Sb Doped SnO2( ATO) nanofiber/Self­standing/Flexible conducting film

分类

化学化工

引用本文复制引用

孔壮,李勇,鹿现永,朱英,江雷..柔性透明自支撑氧化锡锑电纺纳米纤维膜的制备与表征[J].高等学校化学学报,2015,(1):55-60,6.

基金项目

国家“八六三”计划项目(批准号:2012AA030305)、国家“九七三”计划项目(批准号:2012CB933200)和国家自然科学基金(批准号:51273008,51473008)资助.? Supported by the National High Technology Research and Development Program of China(No.2012AA030305), the National Basic Research Program of China(No.2012CB933200) and the National Natural Seience Foundation of China(Nos.51273008,51473008) (批准号:2012AA030305)

高等学校化学学报

OA北大核心CSCDCSTPCD

0251-0790

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