高等学校化学学报Issue(2)：215-220,6.DOI:10.7503/cjcu20140957
以5-叠氮间苯二甲酸为有机酸配体的配位聚合物的合成与表征
Synthesis and Characterization of Coordination Polymers Based on 5-Azidoisophthalic Acid
摘要
Abstract
Four coordination polymers, Co(aip)(py)3(1), Co(aip)(4,4’-bipy)(2), Mn(aip)(4,4’-bipy)(3) and Mn(aip)(dptz)(4)[Py: pyridine; 4,4’-bipy: 4,4’-dipyridyl; dptz: 3,6-bis(4-pyridyl)-1,2,4,5-tetrazine] were synthesized by the reaction of 5-azidoisophthalic acid(H2aip) and auxiliary ligands with transition metal. The structures of the complexes were characterized by single crystal X-ray diffraction, powder X-ray diffraction, elemental analyses, infrared spectroscopy and thermal-gravimetric analysis. The structural analyses of compound 1 show that the complex belongs to the monoclinic system, and the space group is C2/c with a 1D chain structure. Compounds 2 and 3 belong to the monoclinic system, and the space group is C2/m with 2D network structures. For compound 4, the space group is P1 with a 2D network. The magnetic properties were also characterized. The results reveal that anti-ferromagnetic interaction exists in compounds 1—4 .关键词
晶体结构/溶剂热合成/配位聚合物/磁性/5-叠氮间苯二甲酸配体Key words
Crystal structure/Solvothermal synthesis/Coordination polymer/Magnetic property/5-Azido-isophthalic acid ligand分类
化学化工引用本文复制引用
马本华,彭宇,华佳,施展..以5-叠氮间苯二甲酸为有机酸配体的配位聚合物的合成与表征[J].高等学校化学学报,2015,(2):215-220,6.基金项目
国家自然科学基金(批准号:21371069)和国家“八六三”计划项目(批准号:2013AA031702)资助 （批准号:21371069）
