高等学校化学学报Issue(4)：745-750,6.DOI:10.7503/cjcu20140728
微纳复合结构MFe2 O4负极材料的可控合成与性能
Controllable Synthesis and Performance of Micro-nano Structure MFe2 O4(M=Zn, Co) in Lithium-ion Batteries
摘要
Abstract
Micro-nano structure MFe2O4(M=Zn, Co) materials were synthesized directly by hydrothermal method. The structural and morphological properties of the samples were investigated by means of X-ray diffraction( XRD) and transmission electron microscopy( TEM) . The electrochemical performance of MFe2 O4 ( M=Zn, Co) was examined by galvanostatic charge-discharge test and electrochemical alternate current( AC) impedance technique. The results show that hollow sphere CoFe2 O4 and ZnFe2 O4 have a reversible capacity of 1180 and 655 mA·h/g after 50 cycles, which are higher than those of solid sphere materials. At the same time, the formation mechanism of different morphology was studied.关键词
微纳复合结构/溶剂热合成/负极材料/锂离子电池Key words
Micro-nano structure/Hydrothermal synthesis/Anode material/Lithium-ion battery分类
化学化工引用本文复制引用
岳红云,王秋娴,张雪,华双,马华,岳东媛,杨书廷..微纳复合结构MFe2 O4负极材料的可控合成与性能[J].高等学校化学学报,2015,(4):745-750,6.基金项目
国家“八六三”计划项目(批准号:2013AA110104)、河南师范大学博士科研启动费支持课题(批准号：qd12124)和河南省教育厅重点科技攻关计划项目(批准号:13A150518)资助.覮Supported by the National High Technology Research and Development Program of China(No.2013AA110104), the Research Fund for the Doctoral Program of Henan Normal University, China(No. qd12124) and the Key Project of Science and Technology of Henan Educational Commit-tee, China(No.13A150518) （批准号:2013AA110104）
