固体火箭技术Issue(2)：233-237,5.DOI:10.7673/j.issn.1006-2793.2014.02.017
高能球磨法制备Al／B／Fe2 O3纳米复合含能材料
Preparation of Al/B/Fe2 O3 nano-composite energetic materials by high energy ball milling
摘要
Abstract
In order to reduce the acidic impurity of B2 O3 and H3 BO3 on the surface of amorphous boron powder and improve the efficiency in the use of boron powder,sodium hydroxide( NaOH)was firstly used to modify the amorphous boron.Then the orthogonal experiment was carried out to optimize the parameters of high energy ball milling for the formation of the Al/B composite.On the ba-sis of Al/B binary nano-composite,the Al/B/Fe2 O3 nano-composite energetic materials were prepared through the high energy ball milling.X-Ray Diffraction ( XRD), Scanning Electron Microscopy ( SEM), Differential scanning calorimetry, X-ray photoelectron spectroscopy were used to characterize the microstructure of composite materials. The results show the content of boron element on the surface of boron particles is increased by 15%,and the influencing order of parameters on the average particle diameter of the composite is as follows:milling time>milling speed>quantity ratio of Al to B>weight ratio of ball to powder.And the optimal HEBM parameters are milling time 12 h,ball-to-powders ratio 20 ∶ 1,milling speed 300 r/min respectively.The macro-particle size of Al/B/Fe2 O3 nano-composite is 3.89μm,with the increasing content of the boron in the Al/B/Fe2 O3 composite,the exothermic heat al-so increases.关键词
纳米复合含能材料/硼提纯/高能球磨法/正交试验Key words
nano-composite energetic materials/boron purification/high energy ball milling/orthogonal experiment分类
航空航天引用本文复制引用
申连华,李国平,罗运军,高坤,柴春鹏,葛震..高能球磨法制备Al／B／Fe2 O3纳米复合含能材料[J].固体火箭技术,2014,(2):233-237,5.基金项目
总装预研项目（51328050211）。 （）
