固体火箭技术Issue(2)：291-294,300,5.DOI:10.7673/j.issn.1006-2793.2015.02.026
SiC-ZrC陶瓷单组分前驱体树脂的制备与性能
Synthesis and properties of zirconium-containing preceramic resin for SiC-ZrC ceramics
黄传进 1王明存1
作者信息
- 1. 北京航空航天大学 化学与环境学院，北京 100191
- 折叠
摘要
Abstract
Novel polyzirconosilane resin was prepared by Wurtz-Fittig copolymerization of amine stablized zirconium chloride, methyldichlorosilane and trimethylchlorosilanes, for the application of single source precursor of SiC-ZrC multicomponent ceramic (zirconium content was easily tailored).The polyzirconosilane resin was viscous liquid at ambient conditions,and its rehology was readily tailored catering to the composite process of PIP technique(Precursor-Infiltration-and-Pyrolysis).The polyzirconosilane resin underwent thermal cure at 110~200℃ to form yellowish solid,and the cured polyzirconosilane was transformed to SiC-ZrC monolith at a yield of >60% at 1 000~1 400℃. The polyzirconosilane derived SiC-ZrC exhibits ultra-high thermo-oxidation resistance in air atmophere at high temperatures.The polyzirconosilane preceramic resin would be an ideal candidate for ultra-high temperature ce-ramics in the applications of oxidation conditions.关键词
SiC-ZrC/陶瓷前驱体/合成/裂解/高温/耐氧化Key words
SiC-ZrC/preceramic/synthesis/pyrolysis/ultra-high temperature/anti-oxidation分类
航空航天引用本文复制引用
黄传进,王明存..SiC-ZrC陶瓷单组分前驱体树脂的制备与性能[J].固体火箭技术,2015,(2):291-294,300,5.
