固体火箭技术Issue(3)：392-395,4.DOI:10.7673/j.issn.1006-2793.2015.03.018
三（叠氮乙酰氧甲基）硝基甲烷的合成与性能
Synthesis and properties oftri(azido-acetoxymethyl) nitromethane
摘要
Abstract
TMNTA was synthesized using tris( hydroxymethyl) nitromethane as raw material,via the two⁃step reactions of esterif⁃ication, azidonation with a total yield of 83.0%.Its structures were confirmed by IR,NMR and elemental analysis.The affecting fac⁃tors of azidonation were studied.The optimum conditions of the reactions were:nexp:ntheory=1.10 for NaN3(molar ratio),10%~25% of the total volume of acetone⁃H2 O and reaction time 1 h. Some physicochemical properties of TMNTA were obtained by the tests.Results show that the density is 1.45 g/cm3,decomposition temperature is 235.7℃,glass transition temperature is-26.23 ℃, H50=44.7cm(2 kg),friction sensitivity is 4%(66°).关键词
有机化学/有机合成/三(叠氮乙酰氧甲基)硝基甲烷/性能Key words
organic chemistry/organic synthesis/TMNTA/property分类
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刘亚静,莫洪昌,陈斌,张丽洁,高福磊,姬月萍..三（叠氮乙酰氧甲基）硝基甲烷的合成与性能[J].固体火箭技术,2015,(3):392-395,4.基金项目
装预研项目（40406030101）。 （）
